Microwave-assisted sidewall functionalization of single-wall carbon nanotubes by Diels-Alder cycloaddition.
نویسندگان
چکیده
The first Diels-Alder cycloaddition of o-quinodimethane to SWNT has been performed under microwave irradiation.
منابع مشابه
The confined space inside carbon nanotubes can dictate the stereo- and regioselectivity of Diels-Alder reactions.
Chemical reactions inside carbon nanotubes can yield unusual outcomes. Molecular dynamics simulations show that within the confined space of carbon nanotubes, the 1,4-exo adduct of a Diels-Alder cycloaddition may be produced instead of the 9,10-adduct, which is favoured in bulk. The likely product is highly dependent on the nanotube radius and reactant size.
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ورودعنوان ژورنال:
- Chemical communications
دوره 15 شماره
صفحات -
تاریخ انتشار 2004